Mercallite is a rare potassium hydrogen sulfate mineral that typically forms as a white efflorescent crust or coating around active volcanic fumaroles. Due to its high solubility, it is rarely found in nature unless collected immediately from dry, arid volcanic environments.

Hardness
2
Mohs
Luster
Vitreous
Streak
White
Transparency
Transparent

Is this mercallite?

5-step field check

Run through these checks against the specimen in your hand. The more boxes tick, the more confident the ID.

  • 1
    Test the hardness
    Try to scratch mercallite with a known reference. Mercallite sits at Mohs 2, softer than the next harder reference, harder than the previous one.
  • 2
    Check the streak
    Drag the specimen across an unglazed porcelain plate. Streak: white.
  • 3
    Read the luster
    Hold the specimen under a strong light. Luster: vitreous.
  • 4
    Match the color range
    Compare against the expected color range: colorless, sky blue.
  • 5
    Look at form & habit
    Crystal system: orthorhombic. Typical habit: stalactitic, tabular.

Often confused with

Mercallite vs. its common look-alikes, and how to tell them apart in the field.

Often found alongside mercallite

Minerals reported to co-occur with mercallite. Spotting these in float or country rock is a strong cue you are in the right ground.

All properties

Chemical formula
KHSO₄
Mohs hardness
2
Density
2.31 g/cm³
Streak
White
Luster
Vitreous
Transparency
Transparent
Crystal system
Orthorhombic
Crystal habit
Stalactitic, tabular
Cleavage
None
Rarity
Rare
Uses
Collector
Host rock
In fumaroles

Where rockhounds find mercallite

Classic worldwide localities

  • Vesuvius, Campania, Italy

Field-hunting tip

Where it forms: In fumaroles. If you start seeing halite, misenite, hieratite in float, you are in the right ground. Typical habit: stalactitic, tabular. Train your eye for that shape before scanning the outcrop.

Common questions

How do you identify mercallite?+
Mohs hardness is 2. Luster: vitreous. The streak is white. Common colors include colorless, sky blue.
Where is mercallite found?+
Notable localities include Vesuvius, Campania, Italy.
What rocks look like mercallite?+
Mercallite is most often confused with Alunogen, Misenite. A quick hardness test and a streak check separate the look-alikes faster than color alone.
What minerals are found with mercallite?+
Mercallite commonly co-occurs with Halite, Misenite, Hieratite, Carobbiite. Spotting any of these in float or country rock is a useful trip signal.
What kind of rock does mercallite form in?+
Where it forms: In fumaroles. Working float back to the host body is the standard way to chase a fresh occurrence.
What is mercallite used for?+
Mercallite is used in collector.

Find mercallite on the map

RockHoundR shows mapped rockhounding spots, access rules, and lets you log every find.

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